Lithium Fluoride(LiF) Properties (25 Facts You Should Know)

Lithium fluoride is an inorganic compound with structure of similar to sodium chloride Let us discuss about various facts related to lithium fluoride in this article.

Lithium fluoride is an ionic compound formed by the combination of an alkali metal, lithium and halogen, Fluorine. It has a bitter or saline like taste with a linear shape. It’s refractive index is found to be 1 .3915. lithium fluoride is substance which is soluble in water and HF and not in ethanol.

Lithium fluoride is prepared by treating Li(OH)2 or Li2CO3 with HF. Let us discuss about the colour, viscosity and density of lithium fluoride in the following sections.

Lithium fluoride IUPAC name

The IUPAC name of lithium fluoride is lithium fluoride.

Lithium fluoride chemical formula

The chemical formula of lithium fluoride is LiF.

lithium fluoride properties
Shape of LiF

Lithium fluoride CAS number

The CAS number of lithium fluoride is 7789-24-4.

Lithium fluoride chemspider ID

The chemspider ID of lithium fluoride is 23007.

Lithium fluoride chemical classification

  • Lithium fluoride is an organic compound which is solid.
  • Lithium fluoride is made up of lithium ion and fluoride ion.
  • Lithium fluoride is formed by the electrostatic attraction of two opposite charges like Li+ and F.

Lithium fluoride molar mass

The molar mass of lithium fluoride is 25.939 gram/mol.

Lithium fluoride colour

The colour of lithium chloride is white or sometimes it can be a transparent crystal.

Lithium fluoride viscosity

The viscosity of lithium fluoride is found to be decreasing when the temperature is increased. According to study when the temperature is increased from 1000 to 1800 Kelvin its viscosity is changes from 1.8 to 0.8 m Pa s.

Lithium fluoride molar density

The molar density of lithium fluoride is 2.635 grams / cm3 .

Lithium fluoride melting point

The melting point of lithium fluoride is 845 degree Celsius or 1118 Kelvin. It is also 1553 degree fahrenheit.

Lithium fluoride boiling point

The boiling point of lithium fluoride is 1676 degree Celsius or 1949 Kelvin. According to fahrenheit scale it is 3049 degree fahrenheit.

Lithium fluoride state at room temperature

Lithium fluoride is found to be a white coloured powder or a transparent crystal which is hygroscopic in nature.

Lithium floride ionic bond

Lithium fluoride is made by the ionic bond between lithium ion and fluoride ion. Lithium lost one of its electron to become Li+ and fluorine accepts that electron to become F. Then they attract each other to form the compound.

Lithium fluoride ionic radius

The ionic radius of lithium fluoride is 1.570.

Lithium fluoride electron configuration

The various orbitals involved in filling electrons are s,p,d and f. Let us discuss about the electronic configuration of LiF.

The electronic configuration of lithium is 1s1 2s1 and Fluorine is 1s1 2s2 2p3.

Lithium fluoride oxidation State

The oxidation state of lithium fluoride is zero.

Lithium fluoride acidity or alkaline

The aqueous solution of lithium fluoride is found to be acidic.

Is Lithium fluoride odourless?

Lithium fluoride is an odourless solid substance with a bitter or saline like taste.

Is Lithium fluoride paramagnetic?

Paramagnetic substance have a permanent dipole moment. Let us check whether Lithium fluoride is paramagnetic or not.

Lithium floride is found to be a diamagnetic substance because all the electrons are paired.

Lithium fluoride hydrates

Lithium fluoride doesn’t form in a type of hydrate as it does not react with oxides.

Lithium fluoride crystal structure

The crystal structure of lithium fluoride a face-centred cubic lattice with the lattice constant value of 403.51 Pico metre.

Lithium fluoride polarity and conductivity

Lithium fluoride is a polar compound with a dipole moment value 6.327 D. It is Polar in nature because of it’s ionic character. Lithium fluoride has 83.9% ionic character. Also the compound is formed by the electrostatic attraction of two opposite charge is the reason for its ionic behaviour.

Lithium fluoride is found be good conductor because it is an ionic compound. Most of the ionic compounds are found to be good in conductivity.

Lithium fluoride reaction with acid

Lithium fluoride react with hydrogen fluoro acid to form Lithium hydrogen fluoride and also with hydrogen chloride to form lithium chloride and hydrogen fluoride.

LiF + HCl → LiCl + HF

LiF + HF → LiHF2

Lithium fluoride reaction with base

Lithium fluoride react with a base like Lithium hydroxide to form a double salt with the formula LiF. LiOH.

LiF + Li(OH)2 → LiF.Li(OH)2

Lithium fluoride reaction with oxide

There is no reaction observed for Lithium fluoride and oxides because of its shielding structure.

Lithium fluoride react with a metal

There is no reaction found in between Lithium fluoride and metal because of Oxygen vacancies.

Conclusion

Lithium chloride is used in Lithium Phosphorus hexa fluoride batteries, electrolysis of fluorine, in vaccum ultraviolet spectrum, radiation detectors and nuclear reactors. When heated Lithium fluoride forms toxic fluoride gas.