11 Sodium Sulfide Uses: Facts You Should Know!

Sodium sulfide is a hygroscopic ionic solid with the formula of Na2S. It is corrosive and has a rotten egg-like smell. Let us discuss various uses of Sodium sulfide (Na2S).

Sodium sulfide is used in a variety of fields, including

  • Textile Industry
  • Leather Industry
  • Paper and Pulp Industry
  • Photographic Industry
  • Rubber Industry
  • Cosmetic Industry
  • Application of dyes
  • Flotation of Ores
  • Regeneration of Silver
  • Thermoplastic Polymer Preparation
  • Oil Refineries

Na2S is readily available in the hydrated form, Na2S. 9H2O. Both anhydrous and hydrous forms are colorless. In this article, we will discuss various uses of sodium sulfide in detail.

Textile Industry

Na2S is used to bleach, dechlorinate, and desulfurize cotton clothes in the textile industry.

Leather Industry

Na2S is used as a dehairing agent in the pre-tanning stage of the leather manufacturing process.

Paper and Pulp Industry

  • Na2S is employed in the paper and pulp industries during the Kraft process.
  • In this procedure, wood chips are treated with Na2S and a hot solution of sodium hydroxide (NaOH) which dissolve the bonds connecting lignin, hemicellulose, and cellulose in wood.
  • The presence of slimes and precipitates in the pulp increases the need for more sodium sulfide to remove them.
paper and pulp
Depolymerization of lignin by sodium sulfide

Photographic Industry

Na2S is used to stop the developing solution from oxidizing in the photography industry.

Rubber Industry

The rubber industry uses yellow Na2S flakes to produce high-quality white rubber.

Cosmetic Industry

The cosmetics industry uses Na2S in depilatory creams.

Application of dye

  • When applied to clothing, Na2S works as a chemical agent to make insoluble sulfur dyes soluble.
  • Sodium sulphide reduces an insoluble pigment, turning it into a liquid substance. At that point, it becomes colorless and is applied to cotton clothes. The pigment and water-insoluble state are then restored after drying and oxidization.
dye
Dye on clothes with the help of sodium sulfide

Flotation of ores

  • Sphalerite is floated from a copper-zinc ore by activating it with cupric tones in the presence of sodium sulfide ions.
  • Chalcopyrite is floated from ore samples wet crushed using iron balls followed by sodium sulfide treatment. 
  • These findings suggested that the relevant mineral surfaces had been cleaned by Na2S.
mineral
Surface of ores getting cleaned by sodium sulfide

Regeneration of Silver

Silver may be recovered from photography trash using Sodium sulphide as re-using the resulting solution becomes challenging in photography.

Thermoplastic Polymer Preparation

The interaction of Na2S and 1,4-dichlorobenzene in solvent results in the production of polyphenyl sulfide polymers (PPSs). Filtration, purification, and drying are performed on the polymer produced. PPS can be created in a linear, branching, or cross-linked form.

PPS
Polymerization by sodium sulfide

Oil Refineries

Na2S is used with surfactants to clean up aquifers polluted with nonaqueous phase liquids for oil recovery.

Conclusion

Sodium sulfide (Na2S)  is applied in various fields, including water cleaning, leather, pulp, and paper industries, and laboratory reagents for polymerization of its versatile nature.